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Issue 20, 2003
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Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

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Abstract

Chiral tetraketone ligands are obtained by Claisen-type condensation of 4-bromoacetophenone with the acetone ketal of L-tartraic acid diethylester and lead with gallium(III) or iron(III) ions in self-assembly processes to dinuclear helicate-type cryptands which are able to bind lithium cations.

Graphical abstract: Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

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Publication details

The article was received on 31 Jul 2003, accepted on 05 Sep 2003, published on 19 Sep 2003 and first published online on 19 Sep 2003


Article type: Communication
DOI: 10.1039/B309026D
Citation: Chem. Commun., 2003, 2526-2527
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    Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

    M. Albrecht, S. Schmid, M. deGroot, P. Weis and R. Fröhlich, Chem. Commun., 2003, 2526
    DOI: 10.1039/B309026D

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