Issue 20, 2003
From the journal:

Chemical Communications

Mechanistic insight into the lanthanide (iii) salt catalysed monoacylation of symmetrical diols from structural models†

Paul A. Clarke,*a   Polly L. Arnold,*a   Martin A. Smith,a   Louise S. Natrajan,a   Claire Wilsona  and  Chuen Chanb  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: paul.clarke@nott.ac.uk, polly.arnold@nott.ac.uk
Fax: 44 115 9513564
Tel: 44 115 9513566

b Medicinal Chemistry, GlaxoSmithKline, Gunnels Wood Road, Stevenage, UK

Abstract

Model studies are presented that suggest the mechanism of the lanthanide(III) salt catalysed mono acylation of symmetrical diols proceeds via chelation of the diol and the anhydride to the lanthanide salt, followed by an ‘intramolecular’ acyl transfer.

Graphical abstract: Mechanistic insight into the lanthanide (iii) salt catalysed monoacylation of symmetrical diols from structural models

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Article information

DOI
https://doi.org/10.1039/B308171K
Article type
Communication
Submitted
17 Jul 2003
Accepted
03 Sep 2003
First published
15 Sep 2003

Chem. Commun., 2003, 2588-2589

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Mechanistic insight into the lanthanide (III) salt catalysed monoacylation of symmetrical diols from structural models

P. A. Clarke, P. L. Arnold, M. A. Smith, L. S. Natrajan, C. Wilson and C. Chan, Chem. Commun., 2003, 2588 DOI: 10.1039/B308171K

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