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Issue 21, 2003
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Single-molecule magnets: control by a single solvent molecule of Jahn–Teller isomerism in [Mn12O12(O2CCH2But)16(H2O)4]

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Abstract

Faster- and slower-relaxing versions of the title Mn12 compound have been obtained in pure forms that crystallize in the same space group and differ only in the identity of one lattice solvent molecule; solvent loss causes isomerization from the faster- to the slower-relaxing form.

Graphical abstract: Single-molecule magnets: control by a single solvent molecule of Jahn–Teller isomerism in [Mn12O12(O2CCH2But)16(H2O)4]

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Publication details

The article was received on 02 Jun 2003, accepted on 05 Sep 2003 and first published on 25 Sep 2003


Article type: Communication
DOI: 10.1039/B306246E
Citation: Chem. Commun., 2003,0, 2672-2673
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    Single-molecule magnets: control by a single solvent molecule of Jahn–Teller isomerism in [Mn12O12(O2CCH2But)16(H2O)4]

    M. Soler, W. Wernsdorfer, Z. Sun, J. C. Huffman, D. N. Hendrickson and G. Christou, Chem. Commun., 2003, 0, 2672
    DOI: 10.1039/B306246E

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