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Issue 15, 2003
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Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

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Abstract

A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si–CH2 groups anchored on the framework; this solid induces 30 % enantioselectivity in the cyanosilylation of benzaldehyde.

Graphical abstract: Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

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Publication details

The article was received on 30 Apr 2003, accepted on 27 May 2003 and first published on 18 Jun 2003


Article type: Communication
DOI: 10.1039/B304814D
Citation: Chem. Commun., 2003,0, 1860-1861
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    Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

    C. Baleizão, B. Gigante, D. Das, M. Alvaro, H. Garcia and A. Corma, Chem. Commun., 2003, 0, 1860
    DOI: 10.1039/B304814D

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