Issue 16, 2003
From the journal:

Chemical Communications

A facile tetrahydrothiophene-catalyzed ylide route to vinyloxiranes†

Kai Li,a   Xian-Ming Denga  and  Yong Tang*a  

* Corresponding authors

a Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 354 Fenglin Lu, Shanghai 200032, China
E-mail: tangy@mail.sioc.ac.cn

Abstract

Access to vinyloxiranes using aldehydes and allylic bromides in the presence of 1–5 mol% tetrahydrothiophene is reported. Both aliphatic and aromatic aldehydes work well in this reaction and the catalyst loading could be reduced as low as 0.5 mol%.

Graphical abstract: A facile tetrahydrothiophene-catalyzed ylide route to vinyloxiranes

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Article information

DOI
https://doi.org/10.1039/B304443B
Article type
Communication
Submitted
24 Apr 2003
Accepted
30 Jun 2003
First published
10 Jul 2003

Chem. Commun., 2003, 2074-2075

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A facile tetrahydrothiophene-catalyzed ylide route to vinyloxiranes

K. Li, X. Deng and Y. Tang, Chem. Commun., 2003, 2074 DOI: 10.1039/B304443B

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