Issue 3, 2003

Molecular recognition. Electrostatic effects in supramolecular self-assembly

Abstract

A di-positively charged metal-based receptor is shown to form 1∶1 or 2∶1 association complexes with rigid, linear two-site guests depending on the site separation, suggesting that electrostatic repulsion controls the association nuclearity.

Graphical abstract: Molecular recognition. Electrostatic effects in supramolecular self-assembly

Supplementary files

Article information

Article type
Communication
Submitted
06 Nov 2002
Accepted
19 Dec 2002
First published
14 Jan 2003

Chem. Commun., 2003, 392-393

Molecular recognition. Electrostatic effects in supramolecular self-assembly

J. D. Crowley, A. J. Goshe and B. Bosnich, Chem. Commun., 2003, 392 DOI: 10.1039/B210957C

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