N–PtIV–H/N–H⋯PtII intramolecular redox equilibrium in a product of H–C(sp2) cleavage and unusual alkane/arene C–H bond selectivity of ([2.1.1]pyridinophane)PtII(CH3)+†
Abstract
T-shaped 14 valence electron (η2-L)PtMe+ (based on DFT geometry optimization, L = [2.1.1]-2,6-pyridinophane) reacts with