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Issue 14, 2002
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Unprecedented 1,3-dipolar cycloaddition of azomethine ylides to ester carbonyl

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Abstract

Fluorinated azomethine ylides generated by the reaction of difluorocarbene with aryl and alkyl imines of O-acylated salicylaldehyde undergo intramolecular 1,3-dipolar cycloaddition across the ester carbonyl to give 2,8-dioxa-6-azabicyclo[3.2.1]octane derivatives.

Graphical abstract: Unprecedented 1,3-dipolar cycloaddition of azomethine ylides to ester carbonyl

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Publication details

The article was received on 09 May 2002, accepted on 13 Jun 2002 and first published on 24 Jun 2002


Article type: Communication
DOI: 10.1039/B204464A
Citation: J. Chem. Soc., Perkin Trans. 1, 2002,0, 1628-1630
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    Unprecedented 1,3-dipolar cycloaddition of azomethine ylides to ester carbonyl

    M. S. Novikov, I. V. Voznyi, A. F. Khlebnikov, J. Kopf and R. R. Kostikov, J. Chem. Soc., Perkin Trans. 1, 2002, 0, 1628
    DOI: 10.1039/B204464A

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