Jump to main content
Jump to site search

Issue 19, 2002
Previous Article Next Article

The preparation of polymer beads by photocationic suspension co-polymerisation of 2-(arylsilyl)ethyl vinyl ethers

Author affiliations

Abstract

Polymer beads have been prepared by photocationic suspension polymerisation of 2-(aryldimethyl)silyl ethers in perfluorooctane in the course of our studies on polymer-supported desymmetrisation of 1-silacyclohexa-2,5-dienes. Good yields of 100–200 μm beads of satisfactory shape have been obtained using a perfluorinated co-polymer as stabilising agent. These beads have no permanent porosity although they have a high nominal cross-linking level. Their swelling in common organic solvents is comparable with those of Merrifield or TentaGel gel-type resins.

Graphical abstract: The preparation of polymer beads by photocationic suspension co-polymerisation of 2-(arylsilyl)ethyl vinyl ethers

Back to tab navigation

Publication details

The article was received on 12 Feb 2002, accepted on 09 Jul 2002 and first published on 03 Sep 2002


Article type: Paper
DOI: 10.1039/B201520J
Citation: J. Chem. Soc., Perkin Trans. 1, 2002,0, 2198-2203
  •   Request permissions

    The preparation of polymer beads by photocationic suspension co-polymerisation of 2-(arylsilyl)ethyl vinyl ethers

    L. Porres, H. Deleuze and Y. Landais, J. Chem. Soc., Perkin Trans. 1, 2002, 0, 2198
    DOI: 10.1039/B201520J

Search articles by author

Spotlight

Advertisements