Issue 8, 2002

Synthesis of enantiomerically pure divinyl- and diallylcarbinols

Abstract

Acylated oxazolidinones and bornane sultams can be cleaved to divinyl- and diallylcarbinols by treatment with vinyl- or allylmetal compounds. For the preparation of divinylcarbinols, acylated bornane sultams are the starting materials of choice, while for the preparation of diallylcarbinols acylated oxazolidinones and bornane sultams work equally well.

Graphical abstract: Synthesis of enantiomerically pure divinyl- and diallylcarbinols

Article information

Article type
Paper
Submitted
28 Jan 2002
Accepted
08 Mar 2002
First published
25 Mar 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 1050-1060

Synthesis of enantiomerically pure divinyl- and diallylcarbinols

B. Schmidt and H. Wildemann, J. Chem. Soc., Perkin Trans. 1, 2002, 1050 DOI: 10.1039/B200976E

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