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Issue 7, 2002
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Total synthesis of bisabolane sesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: utility of catalytic enamine reaction in cyclohexenone synthesis

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Abstract

Total syntheses of α-bisabol-1-one, curcumene, curcuphenol and elvirol have been accomplished via 1,4-conjugate addition of intact aldehydes to vinyl ketones followed by an intramolecular aldol condensation.

Graphical abstract: Total synthesis of bisabolane sesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: utility of catalytic enamine reaction in cyclohexenone synthesis

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Publication details

The article was received on 17 Jan 2002, accepted on 14 Feb 2002 and first published on 01 Mar 2002


Article type: Paper
DOI: 10.1039/B200629B
Citation: J. Chem. Soc., Perkin Trans. 1, 2002, 895-900
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    Total synthesis of bisabolane sesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: utility of catalytic enamine reaction in cyclohexenone synthesis

    H. Hagiwara, T. Okabe, H. Ono, V. P. Kamat, T. Hoshi, T. Suzuki and M. Ando, J. Chem. Soc., Perkin Trans. 1, 2002, 895
    DOI: 10.1039/B200629B

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