Issue 7, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Total synthesis of bisabolanesesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: utility of catalytic enamine reaction in cyclohexenone synthesis

Hisahiro Hagiwara,*a   Tomoyuki Okabe,a   Hiroki Ono,a   Vijayendra P. Kamat,†b   Takashi Hoshi,b   Toshio Suzukib  and  Masayoshi Andob  

* Corresponding authors

a Graduate School of Science and Technology, Niigata University, 8050, 2-nocho, Ikarashi, Niigata 950-2181, Japan

b Faculty of Engineering, Niigata University, 8050, 2-nocho, Ikarashi, Niigata 950-2181, Japan

Abstract

Total syntheses of α-bisabol-1-one, curcumene, curcuphenol and elvirol have been accomplished via 1,4-conjugate addition of intact aldehydes to vinyl ketones followed by an intramolecular aldol condensation.

Graphical abstract: Total synthesis of bisabolane sesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: utility of catalytic enamine reaction in cyclohexenone synthesis

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Article information

DOI
https://doi.org/10.1039/B200629B
Article type
Paper
Submitted
17 Jan 2002
Accepted
14 Feb 2002
First published
01 Mar 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 895-900

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Total synthesis of bisabolane sesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: utility of catalytic enamine reaction in cyclohexenone synthesis

H. Hagiwara, T. Okabe, H. Ono, V. P. Kamat, T. Hoshi, T. Suzuki and M. Ando, J. Chem. Soc., Perkin Trans. 1, 2002, 895 DOI: 10.1039/B200629B

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