Issue 7, 2002
From the journal:

New Journal of Chemistry

Pentanuclear alkoxyaluminium hydrides

Claire J. Carmalt,*a   John D. Mileham,a   Andrew J. P. Whiteb  and  David J. Williamsb  

* Corresponding authors

a Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, UK
E-mail: c.j.carmalt@ucl.ac.uk

b Department of Chemistry, Imperial College of Science, Technology and Medicine, South Kensington, London, UK

Abstract

Reaction of [AlH3(OEt2)] (generated in situ from AlCl3 and 3 equivalents of LiAlH4) with one equivalent of PriOH resulted in the formation of the pentanuclear complex [Al5(μ4-O)(μ-OPri)7H6]. Incomplete reaction of AlCl3 and 3 equivalents of LiAlH4, followed by the addition of PriOH, afforded the novel species [Al5(μ5-O)(μ-OPri)8(Cl)H4]. Both complexes have been structurally characterised.

Graphical abstract: Pentanuclear alkoxyaluminium hydrides

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Article information

DOI
https://doi.org/10.1039/B201773N
Article type
Paper
Submitted
14 Feb 2002
Accepted
04 Apr 2002
First published
31 May 2002

New J. Chem., 2002,26, 902-905

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Pentanuclear alkoxyaluminium hydrides

C. J. Carmalt, J. D. Mileham, A. J. P. White and D. J. Williams, New J. Chem., 2002, 26, 902 DOI: 10.1039/B201773N

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