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Issue 7, 2002
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Pentanuclear alkoxyaluminium hydrides

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Abstract

Reaction of [AlH3(OEt2)] (generated in situ from AlCl3 and 3 equivalents of LiAlH4) with one equivalent of PriOH resulted in the formation of the pentanuclear complex [Al54-O)(μ-OPri)7H6]. Incomplete reaction of AlCl3 and 3 equivalents of LiAlH4, followed by the addition of PriOH, afforded the novel species [Al55-O)(μ-OPri)8(Cl)H4]. Both complexes have been structurally characterised.

Graphical abstract: Pentanuclear alkoxyaluminium hydrides

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Publication details

The article was received on 14 Feb 2002, accepted on 04 Apr 2002 and first published on 31 May 2002


Article type: Paper
DOI: 10.1039/B201773N
Citation: New J. Chem., 2002,26, 902-905
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    Pentanuclear alkoxyaluminium hydrides

    C. J. Carmalt, J. D. Mileham, A. J. P. White and D. J. Williams, New J. Chem., 2002, 26, 902
    DOI: 10.1039/B201773N

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