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Issue 5, 2002
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Tri-s-triazine derivatives. Part I. From trichloro-tri-s-triazine to graphitic C3N4 structures

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Abstract

The first detailed structural characterisation of a functionalised tri-s-triazine derivative, trichloro-tri-s-triazine, is reported, which is a promising starting material for numerous compounds including graphitic C3N4 phases. DFT calculations show that a C3N4 structure based on tri-s-triazine should exist and that it is ∼30 kJ mol−1 more stable than the previously reported C3N4 phase of lowest energy.

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Publication details

The article was received on 11 Dec 2001, accepted on 19 Feb 2002 and first published on 15 Apr 2002


Article type: Letter
DOI: 10.1039/B111062B
Citation: New J. Chem., 2002,26, 508-512
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    Tri-s-triazine derivatives. Part I. From trichloro-tri-s-triazine to graphitic C3N4 structures

    E. Kroke, M. Schwarz, E. Horath-Bordon, P. Kroll, B. Noll and A. D. Norman, New J. Chem., 2002, 26, 508
    DOI: 10.1039/B111062B

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