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Issue 9, 2002
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Selective binding of very hydrophilic H2PO4 anion by a hydrogen-bonding receptor adsorbed at the 1,2-dichloroethane–water interface

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Abstract

A thiourea-functionalized benzo-15-crown-5 (TU-B15C5), adsorbed at the 1,2-dichloroethane–water interface, can bind H2PO4 selectively over hydrophobic anions (H2PO4 > Cl, ClO4, Br, CH3COO) via the formation of hydrogen bonds.

Graphical abstract: Selective binding of very hydrophilic H2PO4− anion by a hydrogen-bonding receptor adsorbed at the 1,2-dichloroethane–water interface

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Publication details

The article was received on 26 Apr 2002, accepted on 14 Jun 2002 and first published on 29 Jul 2002


Article type: Letter
DOI: 10.1039/B203881A
Citation: New J. Chem., 2002,26, 1102-1104
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    Selective binding of very hydrophilic H2PO4 anion by a hydrogen-bonding receptor adsorbed at the 1,2-dichloroethane–water interface

    K. Shigemori, S. Nishizawa, T. Yokobori, T. Shioya and N. Teramae, New J. Chem., 2002, 26, 1102
    DOI: 10.1039/B203881A

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