Jump to main content
Jump to site search
Publishing
Advanced

Issue 6, 2002
Previous Article Next Article

Structural and electrochemical properties of Li(Fe, Co)xMn2 −xO4 solid solution as 5 V positive electrode materials for Li secondary batteries

Hikari Shigemura,ab  Mitsuharu Tabuchi,*a  Hironori Kobayashi,a  Hikari Sakaebe,a  Atsushi Hiranoc  and  Hiroyuki Kageyamaa 
Author affiliations

* Corresponding authors

a Special Division of Green Life Technology, National Institute of Advanced Industrial Science and Technology (AIST), Osaka, Japan
E-mail: m-tabuchi@aist.go.jp

b New Energy and Industrial Technology Development Organization (NEDO), Tokyo, Japan

c Faculty of Engineering, Mie University, Mie, Japan

Abstract

Solid solutions, Li(Fe, Co)xMn2 − xO4 (0 ≤ x ≤ 0.5 for Fe, 0 ≤ x ≤ 1.0 for Co) were synthesized by solid state reaction at 1023–1073 K in O2 atmosphere. The compositional dependence of lattice parameters and cation distribution was studied by neutron diffraction Rietveld refinement. It was revealed that Fe and Co partially occupied tetrahedral 8a sites and the 1∶3 and 1∶1 ordering did not occur on Fe (Co) and Mn ions in octahedral 16d sites. X-Ray absorption fine structure (XAFS) analysis showed the variation of valences and metal–oxygen interatomic distances of Mn, Fe, and Co. The Fe–O distance was longer whereas the Co–O distance was shorter compared to the averaged M16d–O32e distance calculated from the lattice parameters. Charge and discharge properties were studied in voltage range 3.0–5.3 V vs. Li/Li+.

Graphical abstract: Structural and electrochemical properties of Li(Fe, Co)xMn2 − xO4 solid solution as 5 V positive electrode materials for Li secondary batteries

Back to tab navigation
Download options Please wait...

Publication details

The article was received on 18 Jan 2002, accepted on 20 Mar 2002 and first published on 19 Apr 2002


Article type: Paper
DOI: 10.1039/B200690C
Citation: J. Mater. Chem., 2002,12, 1882-1891
  •   Request permissions

    Structural and electrochemical properties of Li(Fe, Co)xMn2 − xO4 solid solution as 5 V positive electrode materials for Li secondary batteries

    H. Shigemura, M. Tabuchi, H. Kobayashi, H. Sakaebe, A. Hirano and H. Kageyama, J. Mater. Chem., 2002, 12, 1882
    DOI: 10.1039/B200690C

    If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using RightsLink. Go to our Instructions for using RightsLink page for details.

    Authors contributing to RSC publications (journal articles, books or book chapters) do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      Reproduced from Ref. XX with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry.
    • For reproduction of material from PCCP:
      Reproduced from Ref. XX with permission from the PCCP Owner Societies.
    • For reproduction of material from PPS:
      Reproduced from Ref. XX with permission from the European Society for Photobiology, the European Photochemistry Association, and The Royal Society of Chemistry.
    • For reproduction of material from all other RSC journals and books:
      Reproduced from Ref. XX with permission from The Royal Society of Chemistry.

    If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from".

    In all cases the Ref. XX is the XXth reference in the list of references.

    If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. contained in this article in third party publications or in a thesis or dissertation provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC
    • For reproduction of material from PCCP:
      [Original citation] - Reproduced by permission of the PCCP Owner Societies
    • For reproduction of material from PPS:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC
    • For reproduction of material from all other RSC journals:
      [Original citation] - Reproduced by permission of The Royal Society of Chemistry

    If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements