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Issue 5, 2002
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Organic/inorganic hybrids by ‘living’/controlled ATRP grafting from layered silicates

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Abstract

‘Living’/controlled radical graft polymerisation via the atom transfer radical polymerisation (ATRP) route has been carried out from ATRP initiator-modified layered silicate. The grafted polymer chains were detached from the solid in order to prove the well-known ATRP features. X-Ray diffraction measurements at different times of conversion demonstrate an increase of delamination as a result of increasing chain length of the grafts which finally results in a fully dispersed polymer silicate nanocomposite.

Graphical abstract: Organic/inorganic hybrids by ‘living’/controlled ATRP grafting from layered silicates

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Publication details

The article was received on 26 Nov 2001, accepted on 13 Feb 2002 and first published on 26 Mar 2002


Article type: Paper
DOI: 10.1039/B110819K
Citation: J. Mater. Chem., 2002,12, 1351-1354
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    Organic/inorganic hybrids by ‘living’/controlled ATRP grafting from layered silicates

    H. Böttcher, M. L. Hallensleben, S. Nuß, H. Wurm, J. Bauer and P. Behrens, J. Mater. Chem., 2002, 12, 1351
    DOI: 10.1039/B110819K

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