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Volume 121, 2002
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Novel method for the investigation of single nanoparticle reactivity

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Abstract

The reactivity of planar surfaces has been well investigated but there are many new unexplored aspects involved in the reactivity of nanoparticle surfaces. Most investigative methods only measure the average properties of the particles present on the surface. In order to investigate the local reactivity of nanoparticles, the STM tip electrode can be used as a local sensor. The feasibility of this approach is demonstrated by detecting some of the hydrogen (through the hydrogen oxidation reaction current at the tip) which is evolved at a single Pd particle on the Au(111) substrate at a constant distance from the tip. In principle, it is thereby possible to determine the reactivities of surfaces on a nanometre scale. To avoid interference from different reactive particles it is essential to use electrodes with a very low particle density. Hence, in this investigation electrodes with single Pd particles which were deposited from the STM tip onto the substrate are used. Results of potential-dependent measurements at single metal nanoparticles will be shown and the possibilities and limitations of the approach will also be discussed.

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Publication details

The article was received on 02 Jan 2002, accepted on 14 Jan 2002 and first published on 17 Jul 2002


Article type: Paper
DOI: 10.1039/B200014H
Citation: Faraday Discuss., 2002,121, 365-372
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    Novel method for the investigation of single nanoparticle reactivity

    J. Meier, K. A. Friedrich and U. Stimming, Faraday Discuss., 2002, 121, 365
    DOI: 10.1039/B200014H

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