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Issue 20, 2002
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A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)7Al(OH)6Mo6O18]n·4nH2O

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Abstract

The structure of the complex [La(H2O)7Al(OH)6Mo6O18]n·4nH2O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange “head to tail” in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network.

Graphical abstract: A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)7Al(OH)6Mo6O18]n·4nH2O

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Publication details

The article was received on 22 Jul 2002, accepted on 03 Sep 2002 and first published on 10 Sep 2002


Article type: Communication
DOI: 10.1039/B207149E
Citation: J. Chem. Soc., Dalton Trans., 2002,0, 3781-3782
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    A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)7Al(OH)6Mo6O18]n·4nH2O

    V. Shivaiah, P. V. Narasimha Reddy, L. Cronin and S. K. Das, J. Chem. Soc., Dalton Trans., 2002, 0, 3781
    DOI: 10.1039/B207149E

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