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Issue 11, 2002
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NMR studies of the molecular dynamics of tert-butyl chloride confined in the mesoporous molecular sieve MCM-41

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Abstract

The molecular dynamics of tert-butyl chloride (TBC) confined in the molecular sieve MCM-41 were investigated by measuring NMR linewidths, lineshapes, and 1H and 2H spin–lattice relaxation times. The temperatures of phase transitions of confined TBC are different from those in bulk. The behaviour of confined TBC can be explained assuming that the guest molecules form two kinds of molecular layers, one located at the pore surface and the other at the centre of the pore.

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Publication details

The article was received on 17 Jan 2002, accepted on 22 Feb 2002 and first published on 30 Apr 2002


Article type: Paper
DOI: 10.1039/B200634K
Citation: Phys. Chem. Chem. Phys., 2002,4, 2392-2397
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    NMR studies of the molecular dynamics of tert-butyl chloride confined in the mesoporous molecular sieve MCM-41

    L. Wasyluk, B. Peplinska, J. Klinowski and S. Jurga, Phys. Chem. Chem. Phys., 2002, 4, 2392
    DOI: 10.1039/B200634K

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