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Issue 24, 2002
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New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

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Abstract

The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)10(OMe)6(F)10(BTA)20(BTAH)2(MeOH)13(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

Graphical abstract: New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

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Publication details

The article was received on 26 Sep 2002, accepted on 07 Nov 2002 and first published on 18 Nov 2002


Article type: Communication
DOI: 10.1039/B209445B
Citation: Chem. Commun., 2002,0, 2974-2975
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    New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

    L. F. Jones, E. K. Brechin, D. Collison, A. Harrison, S. J. Teat and W. Wernsdorfer, Chem. Commun., 2002, 0, 2974
    DOI: 10.1039/B209445B

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