Issue 24, 2002
From the journal:

Chemical Communications

New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

Leigh F. Jones,a   Euan K. Brechin,*a   David Collison,*a   Andrew Harrison,b   Simon J. Teatc  and  Wolfgang Wernsdorferd  

* Corresponding authors

a Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: euan.k.brechin@man.ac.uk, david.collison@man.ac.uk
Fax: (+44)161-275-4616
Tel: (+44)161-275-7857

b Department of Chemistry, Edinburgh University, Edinburgh, UK

c CLRC Daresbury Laboratory, Warrington, Cheshire, Daresbury, UK

d Laboratoire Louis Neel-CNRS, Cedex 9, 38042 Grenoble, France

Abstract

The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)10(OMe)6(F)10(BTA)20(BTAH)2(MeOH)13(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

Graphical abstract: New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

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Article information

DOI
https://doi.org/10.1039/B209445B
Article type
Communication
Submitted
26 Sep 2002
Accepted
07 Nov 2002
First published
18 Nov 2002

Chem. Commun., 2002, 2974-2975

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New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

L. F. Jones, E. K. Brechin, D. Collison, A. Harrison, S. J. Teat and W. Wernsdorfer, Chem. Commun., 2002, 2974 DOI: 10.1039/B209445B

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