Issue 24, 2002

New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

Abstract

The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)10(OMe)6(F)10(BTA)20(BTAH)2(MeOH)13(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

Graphical abstract: New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

Supplementary files

Article information

Article type
Communication
Submitted
26 Sep 2002
Accepted
07 Nov 2002
First published
18 Nov 2002

Chem. Commun., 2002, 2974-2975

New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

L. F. Jones, E. K. Brechin, D. Collison, A. Harrison, S. J. Teat and W. Wernsdorfer, Chem. Commun., 2002, 2974 DOI: 10.1039/B209445B

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