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Issue 16, 2002
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Fusion and planarization of a quinoidal porphyrin dimer

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Abstract

The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the π-system and reduces the optical HOMO–LUMO gap while increasing the gap between the first oxidation and reduction potentials.

Graphical abstract: Fusion and planarization of a quinoidal porphyrin dimer

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Publication details

The article was received on 07 May 2002, accepted on 21 Jun 2002 and first published on 08 Jul 2002


Article type: Communication
DOI: 10.1039/B204265G
Citation: Chem. Commun., 2002,0, 1662-1663
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    Fusion and planarization of a quinoidal porphyrin dimer

    I. M. Blake, A. Krivokapic, M. Katterle and H. L. Anderson, Chem. Commun., 2002, 0, 1662
    DOI: 10.1039/B204265G

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