Issue 15, 2002
From the journal:

Chemical Communications

Unexpected side reactions of imidazolium-based ionic liquids in the base-catalysed Baylis–Hillman reaction†

Varinder K. Aggarwal,*a   Ingo Emmea  and  Andrea Mereua  

* Corresponding authors

a School of Chemistry, University of Bristol, Bristol, UK
E-mail: v.aggarwal@bristol.ac.uk

Abstract

Low yields are obtained when the Baylis–Hillman reaction is conducted in the presence of an imidazolium-based ionic liquid due to direct addition of the deprotonated imidazolium salt to the aldehyde. Ionic liquids are evidently not inert.

Graphical abstract: Unexpected side reactions of imidazolium-based ionic liquids in the base-catalysed Baylis–Hillman reaction

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Article information

DOI
https://doi.org/10.1039/B203079A
Article type
Communication
Submitted
28 Mar 2002
Accepted
16 Apr 2002
First published
26 Jun 2002

Chem. Commun., 2002, 1612-1613

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Unexpected side reactions of imidazolium-based ionic liquids in the base-catalysed Baylis–Hillman reaction

V. K. Aggarwal, I. Emme and A. Mereu, Chem. Commun., 2002, 1612 DOI: 10.1039/B203079A

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