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Issue 13, 2002
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3-Component palladium–indium mediated diastereoselective cascade allylation of imines with allenes and aryl iodides

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Abstract

A new palladium–indium diastereoselective cascade allylation of imines using allenes and aryl iodides is described; N-tosyl and N-aryl homoallyl amines were obtained in moderate to good yields and excellent diastereoselectivity was observed when enantiomerically pure N-tert-butanesulfinyl imines were employed in the cascade.

Graphical abstract: 3-Component palladium–indium mediated diastereoselective cascade allylation of imines with allenes and aryl iodides

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Supplementary files

Publication details

The article was received on 25 Mar 2002, accepted on 09 May 2002 and first published on 23 May 2002


Article type: Communication
DOI: 10.1039/B202940E
Citation: Chem. Commun., 2002,0, 1372-1373
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    3-Component palladium–indium mediated diastereoselective cascade allylation of imines with allenes and aryl iodides

    I. R. Cooper, R. Grigg, W. S. MacLachlan, M. Thornton-Pett and V. Sridharan, Chem. Commun., 2002, 0, 1372
    DOI: 10.1039/B202940E

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