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Issue 11, 2002
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Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal–magnesium–alkoxide–diisopropylamides

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Abstract

A series of composite lithium– or sodium–magnesium–alkoxide–diisopropylamides of general formula [{MMg[N(Pri)2]2OR}2] (where M = Li, R = Octn; M = Na, R = Bun or Octn), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.

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Publication details

The article was received on 13 Mar 2002, accepted on 19 Apr 2002 and first published on 03 May 2002


Article type: Communication
DOI: 10.1039/B202549C
Citation: Chem. Commun., 2002,0, 1176-1177
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    Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal–magnesium–alkoxide–diisopropylamides

    K. J. Drewette, K. W. Henderson, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara and R. B. Rowlings, Chem. Commun., 2002, 0, 1176
    DOI: 10.1039/B202549C

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