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Issue 8, 2002
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Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first CrIII hybrid inorganic–organic microporous solids: CrIII(OH)·{O2C–C6H4–CO2}·{HO2C–C6H4–CO2H}x

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Abstract

The first three-dimensional chromium(III) dicarboxylate compounds have been isolated and their structures solved from powder X-ray diffraction data; the flexible framework of these materials delimits large pores.

Graphical abstract: Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first Criii hybrid inorganic–organic microporous solids: Criii(OH)·{O2C–C6H4–CO2}·{HO2C–C6H4–CO2H}x

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Publication details

The article was received on 07 Feb 2002, accepted on 07 Mar 2002 and first published on 18 Mar 2002


Article type: Communication
DOI: 10.1039/B201381A
Citation: Chem. Commun., 2002, 822-823
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    Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first CrIII hybrid inorganic–organic microporous solids: CrIII(OH)·{O2C–C6H4–CO2}·{HO2C–C6H4–CO2H}x

    F. Millange, C. Serre and G. Férey, Chem. Commun., 2002, 822
    DOI: 10.1039/B201381A

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