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Issue 9, 2002
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The Baylis–Hillman reaction in supercritical carbon dioxide: enhanced reaction rates, unprecedented ether formation, and a novel phase-dependent 3-component coupling

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Abstract

The Baylis–Hillman reaction can be efficiently carried out in scCO2 with enhanced reaction rates relative to comparable solution phase reactions; at low pressures, a novel dimerisation is observed which has led to the development of a novel one-pot three component coupling reaction to form highly functionalised ethers.

Graphical abstract: The Baylis–Hillman reaction in supercritical carbon dioxide: enhanced reaction rates, unprecedented ether formation, and a novel phase-dependent 3-component coupling

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Publication details

The article was received on 14 Dec 2001, accepted on 08 Mar 2002 and first published on 03 Apr 2002


Article type: Communication
DOI: 10.1039/B111347J
Citation: Chem. Commun., 2002,0, 968-969
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    The Baylis–Hillman reaction in supercritical carbon dioxide: enhanced reaction rates, unprecedented ether formation, and a novel phase-dependent 3-component coupling

    P. M. Rose, A. A. Clifford and C. M. Rayner, Chem. Commun., 2002, 0, 968
    DOI: 10.1039/B111347J

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