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Issue 4, 2002
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Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex

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Abstract

The metalloporphyrin nitrone complexes [M(oep)(CO)(DMPO)] (M = Ru, Os; oep = octaethylporphyrinato dianion; DMPO = 5,5-dimethyl-1-pyrroline N-oxide) have been prepared: the crystal structure of the Ru complex reveals a sole η1-O binding mode of the nitrone ligand to the metal center.

Graphical abstract: Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex

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Publication details

The article was received on 05 Dec 2001, accepted on 14 Jan 2002 and first published on 31 Jan 2002


Article type: Communication
DOI: 10.1039/B111057H
Citation: Chem. Commun., 2002,0, 380-381
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    Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex

    J. Lee, B. Twamley and G. B. Richter-Addo, Chem. Commun., 2002, 0, 380
    DOI: 10.1039/B111057H

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