Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

Hoi-Shan Chan; Hung-Wing Li; Zuowei Xie

doi:10.1039/B110793C

Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

Hoi-Shan Chan,^a Hung-Wing Li^a and Zuowei Xie*^a

* Corresponding authors

^a Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China
E-mail: zxie@cuhk.edu.hk

Abstract

Treatment of an amido–ytterbium complex with n-BuLi leads to the isolation and structural characterization of a mixed amido–imido–ytterbium or imido–ytterbium complex, respectively, depending upon the molar ratios of the reactants; the Yb–N distance and the linearity of the imido N atom strongly suggest the presence of a formal Yb [double bond, length as m-dash] N multiple bond in these novel complexes.

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Publication details

The article was received on 26 Nov 2001, accepted on 08 Feb 2002 and first published on 27 Feb 2002

Article type: Communication

DOI: 10.1039/B110793C

Citation: Chem. Commun., 2002,0, 652-653

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Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

H. Chan, H. Li and Z. Xie, Chem. Commun., 2002, 0, 652
DOI: 10.1039/B110793C
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Chemical Communications

Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

Abstract

Supplementary files

Publication details

Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

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