Transcyclometalation, a versatile methodology for multiple metal–carbon bond formation with multisite ligands

Harm P. Dijkstra; Martin Albrecht; Gerard van Koten

doi:10.1039/B109516C

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Transcyclometalation, a versatile methodology for multiple metal–carbon bond formation with multisite ligands

Harm P. Dijkstra,^a Martin Albrecht^a and Gerard van Koten*^a

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* Corresponding authors

^a Debye Institute, Department of Metal-Mediated Synthesis, Utrecht University, Padualaan 8, Utrecht, The Netherlands
E-mail: g.vankoten@chem.uu.nl.

Abstract

Transcyclometalation has been successfully applied for the multi-platination and -ruthenation of ‘cartwheel’-type ligand systems containing six potential metal binding sites, thus providing a method for multiple metal–carbon bond formation via C–H bond activation which is superior to established cyclometalation protocols.

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DOI: https://doi.org/10.1039/B109516C
Article type: Communication
Submitted: 18 Oct 2001
Accepted: 03 Dec 2001
First published: 20 Dec 2001

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Chem. Commun., 2002, 126-127

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Transcyclometalation, a versatile methodology for multiple metal–carbon bond formation with multisite ligands

H. P. Dijkstra, M. Albrecht and G. V. Koten, Chem. Commun., 2002, 126 DOI: 10.1039/B109516C

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Chemical Communications

Transcyclometalation, a versatile methodology for multiple metal–carbon bond formation with multisite ligands

Abstract

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Transcyclometalation, a versatile methodology for multiple metal–carbon bond formation with multisite ligands

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