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Issue 23, 2002
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A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO–containing poly(alkoxyamine ester)s

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Abstract

A dynamic covalent polymer incorporating thermally alkoxyamine units in the main chain was synthesized. Due to a radical crossover reaction between the alkoxyamine units, an interchange of the main chains in poly(alkoxyamine ester) was observed on heating.

Graphical abstract: A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO–containing poly(alkoxyamine ester)s

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Publication details

The article was received on 19 Sep 2002, accepted on 11 Oct 2002 and first published on 28 Oct 2002


Article type: Communication
DOI: 10.1039/B209193C
Citation: Chem. Commun., 2002,0, 2838-2839
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    A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO–containing poly(alkoxyamine ester)s

    H. Otsuka, K. Aotani, Y. Higaki and A. Takahara, Chem. Commun., 2002, 0, 2838
    DOI: 10.1039/B209193C

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