A novel organometallic columnar complex containing endohedral silver(i)–ethynediyl binding and exterior silver(i)–aromatic interaction†
Abstract
Unprecedented η3
π-donor behavior of the benzyltrimethylammonium ion is observed in the polymeric silver(I) complex [(PhCH2NMe3)Ag7(C2)(CF3CO2)6]n that comprises a columnar backbone constructed from the fusion of Ag8 square antiprisms each enclosing an