Issue 22, 2002
From the journal:

Chemical Communications

One-pot synthesis of tropinone by tandem (domino) ene-type reactions of acetone silyl enol ethers

Koichi Mikami*a  and  Hirofumi Ohmuraa  

* Corresponding authors

a Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, Japan
E-mail: kmikami@o.cc.titech.ac.jp

Abstract

A synthetic approach for tropane alkaloids on the basis of tandem (domino) ene-type reactions of acetone silyl enol ethers with iminium ions is shown to be triggered by intermolecular ene-type reactions followed by 6-(2,5) silatropic ene-type cyclizations.

Graphical abstract: One-pot synthesis of tropinone by tandem (domino) ene-type reactions of acetone silyl enol ethers

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Article information

DOI
https://doi.org/10.1039/B208066D
Article type
Communication
Submitted
16 Aug 2002
Accepted
10 Oct 2002
First published
23 Oct 2002

Chem. Commun., 2002, 2626-2627

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One-pot synthesis of tropinone by tandem (domino) ene-type reactions of acetone silyl enol ethers

K. Mikami and H. Ohmura, Chem. Commun., 2002, 2626 DOI: 10.1039/B208066D

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