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Issue 20, 2002
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Thioepoxide formation by ring closure of allylthiyl radicals—a novel rearrangement of allylic thionitrites

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Abstract

Tertiary allylic thionitrites undergo thermal rearrangement to α,β-episulfide nitroso dimers via ring closure of allylthiyl radicals.

Graphical abstract: Thioepoxide formation by ring closure of allylthiyl radicals—a novel rearrangement of allylic thionitrites

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Publication details

The article was received on 24 Jul 2002, accepted on 22 Aug 2002 and first published on 18 Sep 2002


Article type: Communication
DOI: 10.1039/B207252C
Citation: Chem. Commun., 2002,0, 2394-2395
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    Thioepoxide formation by ring closure of allylthiyl radicals—a novel rearrangement of allylic thionitrites

    M. Cavero, W. B. Motherwell, P. Potier and J. Weibel, Chem. Commun., 2002, 0, 2394
    DOI: 10.1039/B207252C

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