Issue 18, 2002

A twenty-four membered mixed-metal macrocycle; Synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6

Abstract

The first example of a twenty-four membered mixed p-/s-block macrocycle, cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6 1 has been synthesised and structurally characterised from the reaction between 3-Me-1,2-C6H3(OH)(ONa) and (Me2N)2Sb(CH2)3Sb(NMe2)2.

Graphical abstract: A twenty-four membered mixed-metal macrocycle; Synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6

Supplementary files

Article information

Article type
Communication
Submitted
28 Jun 2002
Accepted
15 Aug 2002
First published
27 Aug 2002

Chem. Commun., 2002, 2150-2151

A twenty-four membered mixed-metal macrocycle; Synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6

M. A. Paver, J. S. Joy and M. B. Hursthouse, Chem. Commun., 2002, 2150 DOI: 10.1039/B206228C

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