Issue 11, 2002
From the journal:

Chemical Communications

N2O decomposition over Fe/ZSM-5: reversible generation of highly active cationic Fe species

Q. Zhu,a   E. J. M. Hensen,*a   B. L. Mojet,b   J. H. M. C. van Wolputa  and  R. A. van Santena  

* Corresponding authors

a Schuit Institute of Catalysis, Laboratory of Inorganic Chemistry and Catalysis, Eindhoven University of Technology, P.O.Box 513, Eindhoven, The Netherlands
E-mail: E.J.M.Hensen@tue.nl

b Department of Chemical Technology, Catalytic Processes and Materials, University of Twente, P.O.Box 217, Enschede, The Netherlands

Abstract

Fe-oxide species in Fe/ZSM-5 (prepared by chemical vapor deposition of FeCl3)—active in N2O decomposition—react with zeolite protons during high temperature calcination to give highly active cationic Fe species, this transformation being reversible upon exposure to water vapor at lower temperature.

Graphical abstract: N2O decomposition over Fe/ZSM-5: reversible generation of highly active cationic Fe species

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Article information

DOI
https://doi.org/10.1039/B202843C
Article type
Communication
Submitted
21 Mar 2002
Accepted
26 Apr 2002
First published
07 May 2002

Chem. Commun., 2002, 1232-1233

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N2O decomposition over Fe/ZSM-5: reversible generation of highly active cationic Fe species

Q. Zhu, E. J. M. Hensen, B. L. Mojet, J. H. M. C. van Wolput and R. A. van Santen, Chem. Commun., 2002, 1232 DOI: 10.1039/B202843C

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