Issue 11, 2002
From the journal:

Chemical Communications

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal–magnesium–alkoxide–diisopropylamides

Katy J. Drewette,a   Kenneth W. Henderson,a   Alan R. Kennedy,a   Robert E. Mulvey,*a   Charles T. O’Haraa  and  René B. Rowlingsa  

* Corresponding authors

a Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: r.e.mulvey@strath.ac.uk

Abstract

A series of composite lithium– or sodium–magnesium–alkoxide–diisopropylamides of general formula [{MMg[N(Pri)2]2OR}2] (where M = Li, R = Octn; M = Na, R = Bun or Octn), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.

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Article information

DOI
https://doi.org/10.1039/B202549C
Article type
Communication
Submitted
13 Mar 2002
Accepted
19 Apr 2002
First published
03 May 2002

Chem. Commun., 2002, 1176-1177

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Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal–magnesium–alkoxide–diisopropylamides

K. J. Drewette, K. W. Henderson, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara and R. B. Rowlings, Chem. Commun., 2002, 1176 DOI: 10.1039/B202549C

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