Issue 10, 2002
From the journal:

Chemical Communications

1,3-Dibromo-2,4,6-trinitrobenzene (DBTNB). Crystal engineering and perfect polar alignment of two-dimensional hyperpolarizable chromophores

Praveen K. Thallapally,a   Gautam R. Desiraju,*a   Muriel Bagieu-Beucher,b   René Masse,*b   Cyril Bourgognec  and  Jean-François Nicoud*c  

* Corresponding authors

a School of Chemistry, University of Hyderabad, Hyderabad 500 046, India
E-mail: desiraju@uohyd.ernet.in

b Laboratoire de Cristallographie associé à l’Université Joseph Fourier, CNRS, BP166, 38042, Grenoble Cedex, France
E-mail: masse@labs.polycnrs-gre.fr

c Groupe des Matériaux Organiques, Institut de Physique et Chimie des Matériaux de Strasbourg, CNRS et Université Louis Pasteur (UMR 7504), 23 rue du Loess, 67037 Strasbourg Cedex, France
E-mail: nicoud@ipcms.u-strasbg.fr

Abstract

1,3-Dibromo-2,4,6-trinitrobenzene (DBTNB), a two-dimensional charge transfer hyperpolarisable chromophore, crystallises in the non-centrosymmetric space group C2 in perfect polar order leading to an intense powder SHG signal at 1.06 μm.

Graphical abstract: 1,3-Dibromo-2,4,6-trinitrobenzene (DBTNB). Crystal engineering and perfect polar alignment of two-dimensional hyperpolarizable chromophores

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Article information

DOI
https://doi.org/10.1039/B201224C
Article type
Communication
Submitted
06 Feb 2002
Accepted
28 Mar 2002
First published
15 Apr 2002

Chem. Commun., 2002, 1052-1053

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1,3-Dibromo-2,4,6-trinitrobenzene (DBTNB). Crystal engineering and perfect polar alignment of two-dimensional hyperpolarizable chromophores

P. K. Thallapally, G. R. Desiraju, M. Bagieu-Beucher, R. Masse, C. Bourgogne and J. Nicoud, Chem. Commun., 2002, 1052 DOI: 10.1039/B201224C

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