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Issue 4, 2002
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A ring expansion reaction of 1,3-oxathiolanes

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Abstract

1,3-Oxathiolanes are efficiently converted, via sulfur ylide intermediates, to 1,4-oxathianes by ring expansion with a silylated diazoacetate in the presence of a copper catalyst.

Graphical abstract: A ring expansion reaction of 1,3-oxathiolanes

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Publication details

The article was received on 23 Nov 2001, accepted on 04 Jan 2002 and first published on 24 Jan 2002


Article type: Communication
DOI: 10.1039/B110754B
Citation: Chem. Commun., 2002,0, 346-347
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    A ring expansion reaction of 1,3-oxathiolanes

    M. Ioannou, M. J. Porter and F. Saez, Chem. Commun., 2002, 0, 346
    DOI: 10.1039/B110754B

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