Issue 5, 2002
From the journal:

Chemical Communications

Cyclohexadiene-trans-diols as versatile starting material in natural product synthesis: short and efficient synthesis of iso-crotepoxide and ent-senepoxide

Volker Lorbach,a   Dirk Franke,a   Martin Niegerb  and  Michael Müller*a  

* Corresponding authors

a Institute of Biotechnology 2, Forschungszentrum Jülich GmbH, Jülich, Germany
E-mail: mi.mueller@fz-juelich.de
Fax: (+49)2461-61-3870

b Department of Inorganic Chemistry, University of Bonn, Gerhard Domagk Str. 1, Bonn, Germany

Abstract

A new synthesis of ent-senepoxide and iso-crotepoxide starting from microbially produced (+)-trans-2,3-dihydroxy-2,3-dihydrobenzoic acid via regio- and stereoselective epoxidation is described.

Graphical abstract: Cyclohexadiene-trans-diols as versatile starting material in natural product synthesis: short and efficient synthesis of iso-crotepoxide and ent-senepoxide

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Article information

DOI
https://doi.org/10.1039/B110420A
Article type
Communication
Submitted
14 Nov 2001
Accepted
21 Jan 2002
First published
07 Feb 2002

Chem. Commun., 2002, 494-495

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Cyclohexadiene-trans-diols as versatile starting material in natural product synthesis: short and efficient synthesis of iso-crotepoxide and ent-senepoxide

V. Lorbach, D. Franke, M. Nieger and M. Müller, Chem. Commun., 2002, 494 DOI: 10.1039/B110420A

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