Issue 3, 2002
From the journal:

Chemical Communications

Immobilized α-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

Kazuo Yamazaki†a  and  Yoshinori Kondo*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama, Aoba-ku, Sendai, Japan
E-mail: ykondo@mail.pharm.tohoku.ac.jp

Abstract

Rh(II)-catalyzed N–H insertion reaction of immobilized α-diazophosphonoacetate with 2-haloanilines followed by Horner–Emmons reaction gave immobilized enaminoesters, which were efficiently cyclized to indoles via intramolecular palladium catalyzed reaction on a polymer support.

Graphical abstract: Immobilized α-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

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Article information

DOI
https://doi.org/10.1039/B109987F
Article type
Communication
Submitted
02 Nov 2001
Accepted
07 Dec 2001
First published
07 Jan 2002

Chem. Commun., 2002, 210-211

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Immobilized α-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

K. Yamazaki and Y. Kondo, Chem. Commun., 2002, 210 DOI: 10.1039/B109987F

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