Utilization of industrial waste materials. Part 20. Stereoselective cycloaddition of silylenes and a disilene to an enantiomerically pure cyclic ketimine derived from an industrial waste material

Nikolai Graf von Keyserlingk; Jürgen Martens; Detlev Ostendorf; Wolfgang Saak; Manfred Weidenbruch

doi:10.1039/B008708O

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Utilization of industrial waste materials. Part 20.¹ Stereoselective cycloaddition of silylenes and a disilene to an enantiomerically pure cyclic ketimine derived from an industrial waste material

Nikolai Graf von Keyserlingk,^a Jürgen Martens,*^a Detlev Ostendorf,^a Wolfgang Saak^a and Manfred Weidenbruch*^a

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* Corresponding authors

^a Department of Chemistry, University of Oldenburg, Oldenburg, Germany
E-mail: juergen.martens@uni-oldenburg.de

Abstract

A new enantiomerically pure aromatic cyclic ketimine with two stereogenic centres derived from an industrial waste material has been used as a reactant in novel stereoselective cycloadditions of silylenes and disilenes. The products obtained are chiral non-aromatic organosilanes.

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Crystal structure data TXT (83K)

Article information

DOI: https://doi.org/10.1039/B008708O
Article type: Paper
Submitted: 30 Oct 2000
Accepted: 01 Feb 2001
First published: 02 Mar 2001

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J. Chem. Soc., Perkin Trans. 1, 2001, 706-710

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Utilization of industrial waste materials. Part 20. Stereoselective cycloaddition of silylenes and a disilene to an enantiomerically pure cyclic ketimine derived from an industrial waste material

N. G. von Keyserlingk, J. Martens, D. Ostendorf, W. Saak and M. Weidenbruch, J. Chem. Soc., Perkin Trans. 1, 2001, 706 DOI: 10.1039/B008708O

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Journal of the Chemical Society, Perkin Transactions 1