Hydrothermal synthesis, structure and catalytic property of a novel open-framework oxovanadium arsenate

Yongnan Zhao; Qingsheng Liu; Yafeng Li; Xiangming Chen; Zhenhong Mai

doi:10.1039/B102336P

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Yongnan Zhao,*^a Qingsheng Liu,^b Yafeng Li,^b Xiangming Chen^a and Zhenhong Mai^a

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* Corresponding authors

^a Institute of Physics & Center for Condensed Matter Physics, Chinese Academy of Sciences, Beijing, P. R. China
E-mail: zhaoyn@263.net.

^b Department of Chemistry, Jilin University, Changchun, P. R. China

Abstract

A three-dimensional oxovanadium arsenate has been hydrothermally synthesized and structurally determined, which is composed of novel decavanadium clusters linked by AsO₄ tetrahedra to form large cavities with 12-membered ring windows; catalytic measurements show activity for phenol hydroxylation.

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Supplementary files

Crystal structure data TXT (13K)

Article information

DOI: https://doi.org/10.1039/B102336P
Article type: Communication
Submitted: 13 Mar 2001
Accepted: 11 Apr 2001
First published: 26 Apr 2001

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J. Mater. Chem., 2001,11, 1553-1554

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