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Issue 7, 2001
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Chiral induction upon coordination to form an enantiomeric bis-chelate ruthenium(II)–tris(3-methyl-2-pyridylmethyl)amine complex

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Abstract

Chiral induction to a C3-symmetric and non-prochiral tris(3-methyl-2-pyridylmethyl)amine was achieved upon coordination to a ruthenium(II) center by forming a stable fac–cis bis-chelate complex selectively and 1H NMR spectroscopy showed that the chirality is maintained even in solution.

Graphical abstract: Chiral induction upon coordination to form an enantiomeric bis-chelate ruthenium(II)–tris(3-methyl-2-pyridylmethyl)amine complex

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Publication details

The article was received on 02 Jan 2001, accepted on 19 Feb 2001 and first published on 05 Mar 2001


Article type: Communication
DOI: 10.1039/B100095K
Citation: J. Chem. Soc., Dalton Trans., 2001,0, 958-960
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    Chiral induction upon coordination to form an enantiomeric bis-chelate ruthenium(II)–tris(3-methyl-2-pyridylmethyl)amine complex

    T. Kojima and Y. Matsuda, J. Chem. Soc., Dalton Trans., 2001, 0, 958
    DOI: 10.1039/B100095K

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