Issue 4, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Ruthenium–carbon bond formation viacyclometallation of a nucleobase

Clayton Price,a   Michelle A. Shipman,a   Sarah L. Gummerson,a   Andrew Houlton,*a   William Cleggb  and  Mark R. J. Elsegoodb  

* Corresponding authors

a Department of Chemistry, University of Newcastle upon Tyne, Newcastle upon Tyne, UK
E-mail: andrew.houlton@newcastle.ac.uk

b Crystallography Lab., Department of Chemistry, University of Newcastle upon Tyne, Newcastle upon Tyne, UK

Abstract

The presence of a chelating tether attached to ethylguanine leads to the formation of a metal–carbon bond at C8 of the nucleobase when reacted with trans-[RuCl4(dmso)2]−, in contrast, more typical co-ordination at N7 is seen in the absence of the tether.

Graphical abstract: Ruthenium–carbon bond formation via cyclometallation of a nucleobase

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Article information

DOI
https://doi.org/10.1039/B009766G
Article type
Communication
Submitted
06 Dec 2000
Accepted
11 Jan 2001
First published
23 Jan 2001

J. Chem. Soc., Dalton Trans., 2001, 353-354

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Ruthenium–carbon bond formation via cyclometallation of a nucleobase

C. Price, M. A. Shipman, S. L. Gummerson, A. Houlton, W. Clegg and M. R. J. Elsegood, J. Chem. Soc., Dalton Trans., 2001, 353 DOI: 10.1039/B009766G

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