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Issue 20, 2001
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Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

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Abstract

A new manganese(III) oxamato dimer possesing an unprecedented Mn2(μ-O2CR)(μ-OH2⋯O2 CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by ButO2H and O2 in CH2Cl2 at rt.

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Publication details

The article was received on 12 Jun 2001, accepted on 06 Sep 2001 and first published on 01 Oct 2001


Article type: Communication
DOI: 10.1039/B105132F
Citation: Chem. Commun., 2001,0, 2102-2103
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    Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

    G. Blay, I. Fernández, T. Giménez, J. R. Pedro, R. Ruiz, E. Pardo, F. Lloret and M. C. Muñoz, Chem. Commun., 2001, 0, 2102
    DOI: 10.1039/B105132F

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