Topological isomerism in coordination polymers

Alexander J. Blake; Neil R. Brooks; Neil R. Champness; Marcello Crew; Anne Deveson; Dieter Fenske; Duncan H. Gregory; Lyall R. Hanton; Peter Hubberstey; Martin Schröder

doi:10.1039/B103612M

Topological isomerism in coordination polymersElectronic supplementary information (ESI) available: full experimental details. See http://www.rsc.org/suppdata/cc/b1/b103612m/

Alexander J. Blake,^a Neil R. Brooks,^a Neil R. Champness,*^a Marcello Crew,^a Anne Deveson,^b Dieter Fenske,^b Duncan H. Gregory,^a Lyall R. Hanton,*^c Peter Hubberstey^a and Martin Schröder*^a

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* Corresponding authors

^a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: M.Schroder@nottingham.ac.uk, Neil.Champness@nottingham.ac.uk

^b Institut für Anorganische Chemie, Universität Karlsruhe, Engesserstr. Geb-Nr. 30.45, Karlsruhe, Germany

^c Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
E-mail: lhanton@alkali.otago.ac.nz

Abstract

Three coordination polymers formed between CuI and bpds [bpds = bis(4-pyridyl)disulfide] have been prepared and fully characterised illustrating rare examples of solvent dependent topological isomerism in [(CuI)₂(bpds)]_∞; tetrahedral Cu₄I₄cubane junctions are linked to give either necklace or tubular polymers.

Chemical Communications

Topological isomerism in coordination polymersElectronic supplementary information (ESI) available: full experimental details. See http://www.rsc.org/suppdata/cc/b1/b103612m/

Abstract

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