Issue 18, 2001
From the journal:

Chemical Communications

Generation of chromioenamines by reduction of O-acetyloximes with chromium(II) and their applicationElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b1/b105357b/

Kazuhiko Takai,*a   Noriko Katsuraa  and  Yuji Kunisadaa  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushima, Okayama, Japan
E-mail: ktakai@cc.okayama-u.ac.jp

Abstract

Chromioenamines can be generated by treatment of O-acetyloximes with chromium(II) via two steps of one-electron reduction and successive isomerization, and the species react with aldehydes to give γ-amino alcohols after reduction with LiAlH4.

Graphical abstract: Generation of chromioenamines by reduction of O-acetyloximes with chromium(II) and their application

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B105357B
Article type
Communication
Submitted
19 Jun 2001
Accepted
24 Jul 2001
First published
13 Aug 2001

Chem. Commun., 2001, 1724-1725

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Generation of chromioenamines by reduction of O-acetyloximes with chromium(II) and their application

K. Takai, N. Katsura and Y. Kunisada, Chem. Commun., 2001, 1724 DOI: 10.1039/B105357B

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