Issue 2, 2001
From the journal:

Chemical Communications

Reversible α-elimination in the conversion of N–CH3 to N–CH[double bond, length half m-dash]Ir by double C–H activation

Dong-Heon Lee,*a   Junyi Chen,b   Jack W. Faller*b  and  Robert H. Crabtree*b  

* Corresponding authors

a Department of Chemistry, Chonbuk National University, Chonju, 561-756, Korea.
E-mail: dhl@moak.chonbuk.ac.kr

b Yale Chemistry Laboratory, 225 Prospect St., New Haven, CT 06520-8107, USA.
E-mail: jack.faller@yale.edu; robert.crabtree@yale.edu

Abstract

2-Dimethylaminopyridine (pyNMe2; py = 2-pyridyl) reacts with [H2Ir(OCMe2)2L2]+ (L = PPh3) to give a cyclic carbene complex [H2Ir([double bond, length half m-dash]CHN(Me)py)L2]+via an oxidative addition, reversible α-elimination sequence.

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Article information

DOI
https://doi.org/10.1039/B007679L
Article type
Communication
Submitted
18 Sep 2000
Accepted
20 Nov 2000
First published
09 Jan 2001

Chem. Commun., 2001, 213-214

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Reversible α-elimination in the conversion of N–CH3 to N–CH[double bond, length half m-dash]Ir by double C–H activation

D. Lee, J. Chen, J. W. Faller and R. H. Crabtree, Chem. Commun., 2001, 213 DOI: 10.1039/B007679L

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