Issue 2, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

An unusual observation in the rhodium carbenoids: [1,4]-migration in the sugar-derived α-diazo-β-ketoesters

Vijaya N. Desai,a   Nabendu N. Sahaa  and  Dilip D. Dhavale*a  

* Corresponding authors

a Department of Chemistry, Garware Research Centre, University of Pune, Pune, India
E-mail: ddd@chem.unipune.ernet.in

Abstract

In competition with [1,2]-migration, [2,3]-sigmatropic rearrangement and C–H insertion, product formation via an unusual [1,4]-migration is also found to be a prominent process in the rhodium carbenoids derived from sugar α-diazo-β-keto esters 2a–d.

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Article information

DOI
https://doi.org/10.1039/A908453C
Article type
Paper
Submitted
25 Oct 1999
Accepted
09 Nov 1999
First published
27 Jan 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 147-151

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An unusual observation in the rhodium carbenoids: [1,4]-migration in the sugar-derived α-diazo-β-ketoesters

V. N. Desai, N. N. Saha and D. D. Dhavale, J. Chem. Soc., Perkin Trans. 1, 2000, 147 DOI: 10.1039/A908453C

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