Synthesis and structural characterisation of titanium(IV) thiolate compounds
Abstract
Synthetic and structural studies have been performed for two thiolate complexes of titanium(IV). The reaction between Ti(NEt2)4 and 10 equivalents of C6F5SH at room temperature resulted in the formation of the ionic complex [Et2NH2]3[Ti(SC6F5)5][SC6F5]2. The related reaction between Ti(NEt2)4 and 4 equivalents of C6F5SH at room temperature, in the presence of a two